‘The deprotection reaction of 1-phenyl-2-trimethylsilylacetylene has been among the first well-studied experimental works in polaritonic chemistry,’ says Schäfer. ‘Understanding the involved mechanism ...

Sonogashira coupling of trimethylsilylacetylene with 4-alkyloxy-1-iodobenzenes gave 2-(4-(alkyloxy)phenyl)ethynyltrimethylsilanes which undergo deprotection via removal of TMS-group using ...

A chemical genetic strategy for identifying the direct MARylation targets of PARP-7.

We would like to report an explosion that occurred in our laboratory last year while performing an oxidative coupling of trimethylsilylacetylene (TMSA) in a Glaser-Hay reaction. The explosion ...

A new, convenient procedure for the addition reaction of trimethylsilylacetylene to imines is described. Simply treating a solution of aldimine and trimethylsilyl acetylene with catalytic [IrCl(COD)] ...

It has been applied to the coupling of aryl iodides, bromides, triflates, and aryl chloride, as well as pyridine and thiophene derivatives with trimethylsilylacetylene. Excellent yields (80−95%) for ...