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‘The deprotection reaction of 1-phenyl-2-trimethylsilylacetylene has been among the first well-studied experimental works in polaritonic chemistry,’ says Schäfer. ‘Understanding the involved mechanism ...
Sonogashira coupling of trimethylsilylacetylene with 4-alkyloxy-1-iodobenzenes gave 2-(4-(alkyloxy)phenyl)ethynyltrimethylsilanes which undergo deprotection via removal of TMS-group using ...
A chemical genetic strategy for identifying the direct MARylation targets of PARP-7.
We would like to report an explosion that occurred in our laboratory last year while performing an oxidative coupling of trimethylsilylacetylene (TMSA) in a Glaser-Hay reaction. The explosion ...
The diynes required for this procedure are readily synthesized from diaryl ketones by the Corey−Fuchs olefination and subsequent Sonogashira coupling with trimethylsilylacetylene followed by ...
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